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Chemical Engineering Thermodynamics - Section 1 (4)

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Chemical Engineering Thermodynamics - Section 1

Fuels and Combustion is a field and there are problems available to
solve in this category. You will find the MCQs and can solve them easily.

25. 

"At the absolute zero temperature, the entropy of every perfectly crystalline substance becomes zero". This follows from the

A. third law of thermodynamics
B. second law of thermodynamics
C. Nernst heat theorem
D. Maxwell's relations

Answer: Option A

Explanation:

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26. 

The freezing point of a liquid decreases when the pressure is increased, if the liquid __________ while freezing.

A. contracts
B. expands
C. does not change in volume
D. either (a), (b) or (c)

Answer: Option A

Explanation:

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27. 

If the vapour pressure at two temperatures of a solid phase in equilibrium with its liquid phase are known, then the latent heat of fusion can be calculated by the

A. Maxwell's equation
B. Clayperon-Claussius equation
C. Van Laar equation
D. Nernst Heat Theorem

Answer: Option B

Explanation:

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28. 

No work is done by the system, when a reaction occurs at constant

A. volume
B. temperature
C. pressure
D. none of these

Answer: Option A

Explanation:

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29. 

Isobaric process means a constant process.

A. temperature
B. pressure
C. volume
D. entropy

Answer: Option B

Explanation:

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30. 

Entropy of an ideal gas depends upon its

A. pressure
B. temperature
C. both (a) & (b)
D. neither (a) nor (b)

Answer: Option C

Explanation:

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31. 

Keeping the pressure constant, to double the volume of a given mass of an ideal gas at 27°C, the temperature should be raised to __________ °C.

A. 270
B. 327
C. 300
D. 540

Answer: Option B

Explanation:

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32. 

The theoretical minimum work required to separate one mole of a liquid mixture at 1 atm, containing 50 mole % each of n- heptane and n- octane into pure compounds each at 1 atm is

A. -2 RT ln 0.5
B. -RT ln 0.5
C. 0.5 RT
D. 2 RT

Answer: Option B

Explanation:

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